If your response is "I want to minimize pollution" I'm going to stop you right there. Productivity modules ALSO reduce total pollution. Don't believe me? Fill the rocket silo with prod3 modules. You now only need 71/100 rocket parts to build the rocket. That's a 30% pollution reduction for your ENTIRE rocket factory, from the mining, to the smelting, to the processing and final rocket launch. Any extra pollution production at the silo itself amounts to a rounding error when compared to your entire factory, right? Even that dirty blemish can be easily washed away with eff3 beacons. Now add prod3 modules into your labs. Your entire science base + mining operations now produce 17% less pollution. Even the total energy demand of your factory gets reduced, with the silo + labs standing above as the shining peak of energy demand to bind them all together.
So you might want to change the topic to "Productivity modules are sometimes more efficient than efficiencies" because that's completely true!

I'm too busy right now to run through every single iteration of every single module at every step of the process. I don't think it's worth the time but maybe a math nerd might get hooked. Calculating the pollution reduction of productivity modules is very similar to finding the total value of a prod3 in the first place. It's all about the total resources and free production that happens through the assembler. The more free resources and dirty production steps that get cut out of the process, the better it is.